Ünye Bentoniti ile Sulu Ortamdan Amonyum (NH4 +) Adsorbsiyonu

Ramazan Serezli, Ahmet Tabak

Ekoloji, 2013, Issue 87, Pages: 35-42

DOI: https://doi.org/10.5053/ekoloji.2013.875

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Abstract

In this study, ammonium (NH4+) removal from aqueous media was investigated by using bentonit clay. Different concentrations of ammonium ion adsorption from aqueous solutions were examined at a room temperature. Adsorption data were applied to Langmuir and Freundlich models. In addition, the experimental results of adsorption applied to thermodynamic equations of free enthalpy of adsorption process, enthalpy and entropy values were found. Thus, whether voluntary and adsorption effects of temperature on adsorption or not was investigated. In addition, raw and treated clay ammonium (NH4+- bentonite) characterization of samples were established by using thermal analysis and infrared (IR) techniques.

Keywords

adsorption, ammonium, FTIR, thermal analysis, Ünye bentonite

References

  • Akbulut A (1996) Bentonit. MTA Genel Müdürlüğü Yayınları, Eğitim serisi No: 32, Ankara.
  • Alkan M, Demirbaş Ö, Çelikçapa S, Doğan M (2004) Sorption of acid red 57 from aqueous solutions onto sepiolite. Journal of Hazardous Materials 116: 135–145.
  • Al-Kananni T, Mackenzie AF (1991) Sorption and Desorption of Orthophosphate and Pyrophosphate by Mineral Fractions of Soils, Goethite and Kaolinite. Canadian Journal of Soil Science 71: 327-338.
  • Çaglar B, Afsin B, Tabak A, Eren E (2009) Characterization of the cation-exchanged bentonites by XRPD, ATR, DTA/TG analyses and BET measurement. Chemical Engineering Journal 149: 242-248.
  • Dalgıç A, Kavak O (2004) Kil Mineralleri ve Sağlık. Dicle Tıp Dergisi 31(2): 73-78.
  • Eren E (2008) Removal of copper ions by modified Unye clay, Turkey. Journal of Hazardous Materials 162, 235–244.
  • Evans DH, Piermarini PM, Choe KP (2005) The multifunctional fish gill: dominant site of gas exchange, osmoregulation, acid-base regulation, and excretion of nitrogenous waste. Physiological Reviews 85:97-177.
  • Freundlich H (1906) Über die adsorption in lösungen. Zeitschrift für Physikalische Chemie (Leipzig) 57: 385-470.
  • Grim RE (1968) Clay minerology. McGraw-Hill, New York.
  • Haywood GP (1983) Ammonia Toxicity in Teleost Fishes. Canadian Technical Report of Fisheries and Aquatic Sciences 1177: 1-35.
  • Hasçakır B, Dölgen D (2008) Utilization of Clay Minerals in Wastewater Treatment: Organic Matter Removal with Kaolinite. Ekoloji 17(66): 47-54.
  • Ip YK, Chew SF, Randall DJ (2001) Ammonia toxicity, tolerance, and excretion. In: Wright P, Anderson P (eds), Nitrogen Excretion Academic Press, Orlando, Florida 109-148.
  • Iraqi USM, Iraqi E (2000) Sorption of the Pesticide Endosulphan on Two Indian Soils. Journal of Colloid and Interface Science 224: 155-161.
  • İpekoğlu B, Kurşun İ, Bilge Y, Barut A (1997) Türkiye Bentonit Potansiyeline Genel Bir Bakış. 2. Endüstriyel Hammaddeler Sempozyumu. Köse H, Arslan V (eds), 16-17 Ekim 1997, İzmir, 51-69.
  • Juang RS, Wu FC, Tseng RL (1997) The Ability of Activated Clay for the Adsorption of Dyes from Aqueous Solutions Environmental Technology 18(5): 525-531.
  • Kabak H, Basibuyuk M (2012) Adsorption of Diclofenac and Paracetamol by Activated Sludge. Ekoloji 21(85): 41-48.
  • Khalfaoui M, Knani SM, Hachicha A, Lamine AB (2003) New theoretical expressions for the five adsorption type isotherms classified by BET based on statistical physics treatment. Journal of Colloid Interface Science 263(2): 350-356.
  • MacIntyre C, Ellis T, North BP, Turnbull JF (2008) The influences of water quality on the welfare of farmed trout: a review. In: Branson E (ed), Fish Welfare, Blackwell Scientific Publications, London, 150-178.
  • Madejova J (2003) FTIR Techniques in clay mineral studies. Vibrational Spectroscopy 31: 1-10.
  • Madejova J, Bujdak J, Janek, M, Komadel, P (1998) Comparative FT-IR study of structural modifications during acid treatment of dioctahedral smectites and hectorite. Spectrochimica Acta Part A 54:1397-1406.
  • Meade JW (1985) Allowable ammonia for fish culture. Progressive Fish Culturist 47: 135-145.
  • Önal M, Sarıkaya Y (1997) Isıl işlem ve asit aktivasyonun Kütahya bentonitinin fizikokimyasal özellikleri üzerine etkisi. VIII. Işık İ (ed), Ulusal Kil Sempozyumu, 24-27 Eylül 1997, Kütahya, 213-220.
  • Phillips MJ (1985) Analysis of nutrients. In: Stirling HP (ed), Chemical and biological methods of water analysis for aquaculturists, Institute of Aquaculture University of Stirling, Scotland 69-84.
  • Randall DJ, Tsui TKN (2002) Ammonia toxicity in fish. Marine Pollution Bulletin 45:17-23. Serezli R (2011) Sularda Amonyak ve Sucul Canlılarda Etkileri. Yunus Araştırma Bülteni 3: 5-7.
  • Sheng GY, Boyd SA (1998) Relation of Water and Neutral Organic Compounds in the Interlayers of Mixed Ca/Trimethylphenylammonium-Smectites. Clays and Clay Minerals 46(1): 10-17.
  • Tabak A, Afsin B, (2001) Firmly Adsorbed Ammonia and Pyridine Species at Activated Kaolinite Surfaces. Adsorption Science and Technology 19: 673-679.
  • Tabak A (2003) Çeşitli Organo ve Anorgano Killerin Ara Yüzey Özelliklerinin FTIR, XRD, BET, UV-Gör, HPLC ve Termik Analiz Teknikleriyle İncelenmesi. Doktora Tezi, Samsun Ondokuz Mayıs Üniversitesi, Samsun. 180 s.
  • Tabak A, Afsin B, Aygün SF, Icbudak H (2005) Phenanthroline Cu (II) bentonite composite characterization. Journal of Thermal Analysis and Calorimetry 81: 311-314.
  • Tabak A, Afiin B, Aygun SF, Koksal E (2007) Structural characteristic of organo-modified bentonites of different origin. Journal of Thermal Analysis and Calorimetry 87: 375-381.
  • Tabak A, Eren E, Afsin B, Caglar B (2009) Determination of adsorptive properties of a Turkish Sepolite for removal of Reactive Blue 15 anionic dye from aqueous solutions. Journal of Hazardous Materials 161: 1087- 1094.
  • Tabak A, Yilmaz N, Eren E, Cağlar B, Afsin B, Sarihan A (2011) Structural analysis of naproxen-intercalated bentonite (Unye). Chemical Engineering Journal 174: 281-288.
  • Thurston RV, Russo RC (1983) Acute toxicity of ammonia to rainbow trout. Transactions of the American Fisheries Society 112: 696-704.
  • Ugurlu M, Karaoglu MH, Kula I (2010) The Color Removal and Photocatalytic Degradation of Olive Mill Waste Water by Using UV/H2O2/TiO2/Sep. Nanoparticle. Ekoloji 19 (77): 97-106.